Publications
Rosen, T.; Goldberg, I.; Kol, M. Aluminum Complexes of Octahydrophenanthroline‐Based Salophan Ligands: Coordination Chemistry and Activity in the Ring‐Opening Polymerization of Lactide. Eur. J. Inorg. Chem. 2018, 5047-5052. Author Profile.
Rosen, T.; Goldberg, I.; Navarra, W.; Venditto, V.; Kol, M. Block‐Stereoblock Copolymers of Poly(ε‐Caprolactone) and Poly(Lactic Acid). Angew. Chem. Int. Ed. 2018, 57, 7191-7195.
Stasiw, D. E.; Luke, A. M.; Rosen, T.; League, A. B.; Mandal, M.; Neisen, B. D.; Cramer, C. J.; Kol, M.; Tolman, W. B. Mechanism of the Polymerization of rac-Lactide by Fast Zinc Alkoxide Catalysts. Inorg. Chem. 2017, 56, 14366-14372.
Stopper, A.; Rosen, T.; Venditto, V.; Goldberg, I.; Kol, M. Group 4 Metal Complexes of Phenylene-Salalen Ligands in rac-Lactide Polymerization Giving High Molecular Weight Stereoblock Poly(lactic acid). Chem. Eur. J. 2017, 23, 11540–11548. Front Cover, Cover Profile.
Rosen, T.; Goldberg, I.; Navarra, W.; Venditto, V.; Kol, M. Divergent [{ONNN}Mg-Cl] complexes in highly active and living lactide polymerization. Chem. Sci. 2017, 8, 5476-5481.
Rosen, T.; Goldberg, I.; Venditto, V.; Kol, M. Tailor-Made Stereoblock Copolymers of Poly(lactic acid) by a Truly Living Polymerization Catalyst. J. Am. Chem. Soc. 2016, 138, 12041-12044.
Schrekker, C. M. L.; Sokolovicz, Y. C. A.; Raucci, M. G.; Selukar, B. S.; Klitzke, J. S.; Lopes, W.; Leal, C. A. M.; de Souza, I. O. P.; Galland, G. B.; dos Santos, J. -H. Z.; Mauler, R. S.; Kol, M.; Dagorne, S.; Ambrosio, L.; Teixeira, M. L.; Morais, J.; Landers, R.; Fuentefria, A. M.; Schrekker, H. S. Multitask Imidazolium Salt Additives for Innovative Poly(L-lactide) Biomaterials: Morphology Control, Candida spp. Biofilm Inhibition, Human Mesenchymal Stem Cell Biocompatibility, and Skin Tolerance. ACS Appl. Mater. Interfaces, 2016, 8, 21163–21176.
Rosen, T.; Popowski, Y.; Goldberg, I.; Kol, M. Zinc Complexes of Sequential Tetradentate Monoanionic Ligands in the Isoselective Polymerization of rac-Lactide. Chem. Eur. J. 2016, 22, 11533-11536. Inside Cover.
Popowski, Y.; Goldberg, I.; Kol, M. The stereoselectivity of bipyrrolidine-based sequential polydentate ligands around Ru(II). Chem. Commun. 2016, 52, 7932-7934. Back Cover.
Popowski, Y.; Goldberg, I.; Kol, M. Assembling Quasienantiomeric Octahedral Complexes of Different Metals via Quasiracemate Crystallization. Chem. Eur. J. 2016, 22, 5530-5533. Inside Cover.
Press, K.; Goldberg, I.; Kol, M. Mechanistic Insight into the Stereochemical Control of Lactide Polymerization by Salan-Aluminum Catalysts. Angew. Chem. Int. Ed. 2015, 54, 14858-14861.
Pilone, A.; De Maio, N.; Press, K.; Venditto, V.; Pappalardo, D.; Mazzeo, M.; Pellecchia, C.; Kol, M.; Lamberti, M. Ring-opening homo- and co-polymerization of lactides and ε-caprolactone by salalen aluminum complexes. Dalton Trans. 2015, 44, 2157-2165.
Stopper, A.; Press, K.; Okuda, J.; Goldberg, I.; Kol, M. Zirconium Complexes of Phenylene-Bridged {ONSO} Ligands: Coordination Chemistry and Stereoselective Polymerization of rac-Lactide. Inorg. Chem. 2014, 53, 9140–9150.
Pilone, A.; Press, K.; Goldberg, I.; Kol, M.; Mazzeo, M.; Lamberti, M. Gradient Isotactic Multiblock Polylactides from Aluminum Complexes of Chiral Salalen Ligands. J. Am. Chem. Soc. 2014, 136, 2940–2943.
Haas, I.; Dietel, T.; Press, K.; Kol, M.; Kempe, R. Aminopyridinate-FI Hybrids, Their Hafnium and Titanium Complexes, and Their Application in the Living Polymerization of 1-Hexene. Chem. Eur. J. 2013, 19, 14254-14262.
Sauer, A.; Kapelski, A.; Fliedel, C.; Dagorne, S.; Kol, M.; Okuda, J. Structurally well-defined group 4 metal complexes as initiators for the ring-opening polymerization of lactide monomers. Dalton Trans. 2013, 42, 9007-9023.
Press, K.; Venditto, V.; Goldberg, I.; Kol, M. Zirconium and hafnium Salalen complexes in isospecific polymerisation of propylene. Dalton Trans. 2013, 42, 9096-9103.
Sergeeva, E.; Press, K.; Goldberg, I.; Kol, M. Zinc Complexes of Bipyrrolidine-Based Diamine-Diphenolato and Diamine-Diolato Ligands: Predetermination of Helical Chirality Around Tetrahedral Centres. Eur. J. Inorg. Chem. 2013, 3362-3369.
Cohen, A.; Coates, G. W.; Kol, M. Propylene polymerization by C1-symmetric {ONNO'}-type salan zirconium complexes. J. Polym. Sci. A. 2013, 51, 593-600.
Stopper, A.; Okuda, J.; Kol, M. Ring-Opening Polymerization of Lactide with Zr Complexes of {ONSO} Ligands: From Heterotactically Inclined to Isotactically Inclined Poly(lactic acid). Macromolecules 2012, 45, 698–704.
Cohen, A.; Goldberg, I.; Venditto, V.; Kol, M. Oscillating Non-Metallocenes-from-Stereoblock-Isotactic Polypropylene to Isotactic Polypropylene via Zirconium and Hafnium Dithiodiphenolate Catalysts. Eur. J. Inorg. Chem. 2011, 5219-5223.
Buffet, J. -C.; Martin, A. N.; Kol, M.; Okuda, J. Controlled stereoselective polymerization of lactide monomers by group 4 metal initiators that contain an (OSSO)-type tetradentate bis(phenolate) ligand. Polym. Chem. 2011, 2, 2378-2384.
Stopper, A.; Goldberg, I.; Kol, M. Bis(aniline-phenolate) complexes of group 4 metals: Coordination chemistry and lactide polymerization catalysis. Inorg. Chem. Commun. 2011, 14, 715-718.
Press, K.; Cohen, A.; Goldberg, I.; Venditto, V.; Mazzeo, M.; Kol, M. Salalen Titanium Complexes in the Highly Isospecific Polymerization of 1-Hexene and Propylene. Angew. Chem. Int. Ed. 2011, 50, 3529-3532. Back Cover.
Sergeeva, E.; Kopilov, J.; Goldberg, I.; Kol, M. Dithiodiolate Ligands: Group 4 Complexes and Application in Lactide Polymerization. Inorg. Chem. 2010, 49, 3977-3979.
Cohen, A.; Kopilov, J.; Lamberti, M.; Venditto, C.; Kol, M. Same Ligand, Different Metals: Diiodo-Salan Complexes of the Group 4 Triad in Isospecific Polymerization of 1-Hexene and Propylene. Macromolecules 2010, 43, 1689–1691.