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Publications

Rosen, T.; Goldberg, I.; Kol, M. Aluminum Complexes of Octahydrophenanthroline‐Based Salophan Ligands: Coordination Chemistry and Activity in the Ring‐Opening Polymerization of Lactide. Eur. J. Inorg. Chem. 2018, 5047-5052. Author Profile.

 

Rosen, T.; Goldberg, I.; Navarra, W.; Venditto, V.; Kol, M. Block‐Stereoblock Copolymers of Poly(ε‐Caprolactone) and Poly(Lactic Acid). Angew. Chem. Int. Ed. 2018, 57, 7191-7195.

Stasiw, D. E.; Luke, A. M.; Rosen, T.; League, A. B.; Mandal, M.; Neisen, B. D.; Cramer, C. J.; Kol, M.; Tolman, W. B. Mechanism of the Polymerization of rac-​Lactide by Fast Zinc Alkoxide Catalysts. Inorg. Chem. 2017, 56, 14366-14372.

Stopper, A.; Rosen, T.; Venditto, V.; Goldberg, I.; Kol, M. Group 4 Metal Complexes of Phenylene-​Salalen Ligands in rac-​Lactide Polymerization Giving High Molecular Weight Stereoblock Poly(lactic acid). Chem. Eur. J. 2017, 23, 11540–11548. Front Cover, Cover Profile.

Rosen, T.; Goldberg, I.; Navarra, W.; Venditto, V.; Kol, M. Divergent [{ONNN}​Mg-​Cl] complexes in highly active and living lactide polymerization. Chem. Sci. 2017, 8, 5476-5481.

Rosen, T.; Goldberg, I.; Venditto, V.; Kol, M. Tailor-​Made Stereoblock Copolymers of Poly(lactic acid) by a Truly Living Polymerization Catalyst. J. Am. Chem. Soc. 2016, 138, 12041-12044.

Schrekker, C. M. L.; Sokolovicz, Y. C. A.; Raucci, M. G.; Selukar, B. S.; Klitzke, J. S.; Lopes, W.; Leal, C. A. M.; de Souza, I. O. P.; Galland, G. B.; dos Santos, J. -H. Z.; Mauler, R. S.; Kol, M.; Dagorne, S.; Ambrosio, L.; Teixeira, M. L.; Morais, J.; Landers, R.; Fuentefria, A. M.; Schrekker, H. S.  Multitask Imidazolium Salt Additives for Innovative Poly(L-​lactide) Biomaterials: Morphology Control, Candida spp. Biofilm Inhibition, Human Mesenchymal Stem Cell Biocompatibility, and Skin Tolerance. ACS Appl. Mater. Interfaces, 2016, 8, 21163–21176.

Rosen, T.; Popowski, Y.; Goldberg, I.; Kol, M. Zinc Complexes of Sequential Tetradentate Monoanionic Ligands in the Isoselective Polymerization of rac-​Lactide. Chem. Eur. J. 2016, 22, 11533-11536. Inside Cover.

Popowski, Y.; Goldberg, I.; Kol, M. The stereoselectivity of bipyrrolidine-​based sequential polydentate ligands around Ru(II). Chem. Commun. 2016, 52, 7932-7934. Back Cover.

Popowski, Y.; Goldberg, I.; Kol, M. Assembling Quasienantiomeric Octahedral Complexes of Different Metals via Quasiracemate Crystallization. Chem. Eur. J. 2016, 22, 5530-5533. Inside Cover.

Press, K.; Goldberg, I.; Kol, M. Mechanistic Insight into the Stereochemical Control of Lactide Polymerization by Salan-​Aluminum Catalysts. Angew. Chem. Int. Ed. 2015, 54, 14858-14861. 

Pilone, A.; De Maio, N.; Press, K.; Venditto, V.; Pappalardo, D.; Mazzeo, M.; Pellecchia, C.; Kol, M.; Lamberti, M. Ring-​opening homo- and co-​polymerization of lactides and ε-​caprolactone by salalen aluminum complexes. Dalton Trans. 2015, 44, 2157-2165.

Stopper, A.; Press, K.; Okuda, J.; Goldberg, I.; Kol, M. Zirconium Complexes of Phenylene-​Bridged {ONSO} Ligands: Coordination Chemistry and Stereoselective Polymerization of rac-​Lactide. Inorg. Chem. 2014, 53, 9140–9150. 

Pilone, A.; Press, K.; Goldberg, I.; Kol, M.; Mazzeo, M.; Lamberti, M. Gradient Isotactic Multiblock Polylactides from Aluminum Complexes of Chiral Salalen Ligands. J. Am. Chem. Soc. 2014, 136, 2940–2943. 

Haas, I.; Dietel, T.; Press, K.; Kol, M.; Kempe, R. Aminopyridinate-​FI Hybrids, Their Hafnium and Titanium Complexes, and Their Application in the Living Polymerization of 1-​Hexene. Chem. Eur. J. 2013, 19, 14254-14262. 

Sauer, A.; Kapelski, A.; Fliedel, C.; Dagorne, S.; Kol, M.; Okuda, J. Structurally well-​defined group 4 metal complexes as initiators for the ring-​opening polymerization of lactide monomers. Dalton Trans. 2013, 42, 9007-9023. 

Press, K.; Venditto, V.; Goldberg, I.; Kol, M. Zirconium and hafnium Salalen complexes in isospecific polymerisation of propylene. Dalton Trans. 2013, 42, 9096-9103. 

Sergeeva, E.; Press, K.; Goldberg, I.; Kol, M. Zinc Complexes of Bipyrrolidine-​Based Diamine-​Diphenolato and Diamine-​Diolato Ligands: Predetermination of Helical Chirality Around Tetrahedral Centres. Eur. J. Inorg. Chem. 2013, 3362-3369.

 

Cohen, A.; Coates, G. W.; Kol, M. Propylene polymerization by C1-​symmetric {ONNO'}​-​type salan zirconium complexes. J. Polym. Sci. A. 2013, 51, 593-600.

Stopper, A.; Okuda, J.; Kol, M. Ring-​Opening Polymerization of Lactide with Zr Complexes of {ONSO} Ligands: From Heterotactically Inclined to Isotactically Inclined Poly(lactic acid). Macromolecules 201245, 698–704.

Cohen, A.; Goldberg, I.; Venditto, V.; Kol, M. Oscillating Non-​Metallocenes-​from-​Stereoblock-​Isotactic Polypropylene to Isotactic Polypropylene via Zirconium and Hafnium Dithiodiphenolate CatalystsEur. J. Inorg. Chem. 2011, 5219-5223.

Buffet, J. -C.; Martin, A. N.; Kol, M.; Okuda, J. Controlled stereoselective polymerization of lactide monomers by group 4 metal initiators that contain an (OSSO)​-​type tetradentate bis(phenolate) ligand. Polym. Chem. 20112, 2378-2384.

Stopper, A.; Goldberg, I.; Kol, M. Bis(aniline-​phenolate) complexes of group 4 metals: Coordination chemistry and lactide polymerization catalysis. Inorg. Chem. Commun. 201114, 715-718.

Press, K.; Cohen, A.; Goldberg, I.; Venditto, V.; Mazzeo, M.; Kol, M. Salalen Titanium Complexes in the Highly Isospecific Polymerization of 1-​Hexene and Propylene. Angew. Chem. Int. Ed.  201150, 3529-3532. Back Cover.

Sergeeva, E.; Kopilov, J.; Goldberg, I.; Kol, M. Dithiodiolate Ligands: Group 4 Complexes and Application in Lactide Polymerization. Inorg. Chem.  201049, 3977-3979​.

Cohen, A.; Kopilov, J.; Lamberti, M.; Venditto, C.; Kol, M. Same Ligand, Different Metals: Diiodo-​Salan Complexes of the Group 4 Triad in Isospecific Polymerization of 1-​Hexene and Propylene. Macromolecules  201043, 1689–1691.

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